Jawaharlal Nehru Technological University Hyderabad

Jawaharlal Nehru Technological University Hyderabad B.Tech IV SCIENCE AND TECHNOLOGY OF CERAMICS Previous Question Paper (March - 2021 - R16)

B.Tech | IV | I | R16 | March - 2021

Answer PaperPaper Code: 137GXMaximum Marks: 75Time: 3 Hours

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1

With the help of a flow sheet classify the ceramics. Explain.

15 marks

Answer

Ceramics are broadly classified based on their application, chemical composition, and processing methods. The primary classification divides them into traditional and advanced (engineering) ceramics.

The classification flow sheet is as follows:

  • Ceramics
    • Traditional Ceramics
      • Clay products (Bricks, tiles, pottery)
      • Refractories (Fire bricks, crucibles)
      • Glass (Soda-lime, borosilicate)
      • Cements (Portland cement, hydraulic binders)
      • Abrasives (Natural abrasives)
    • Advanced Ceramics
      • Oxide Ceramics (Alumina, Zirconia, Magnesia)
      • Non-Oxide Ceramics (Carbides, Nitrides, Borides)
      • Composite Ceramics (Ceramic matrix composites)

Traditional Ceramics are primarily based on naturally occurring raw materials like clay, silica, and feldspar. They are typically produced in large volumes and are used in construction, domestic applications, and industrial refractory linings. Their properties are generally dictated by the mineralogy of the starting clays and firing temperatures.

Advanced Ceramics, also known as technical or engineering ceramics, are synthesized from high-purity, man-made chemical compounds. They are processed under strictly controlled conditions to achieve specific mechanical, thermal, electrical, or optical properties. These materials are essential for high-performance applications such as aerospace components, electronic substrates, cutting tools, and biomedical implants.

The distinction between these two categories lies in the purity of raw materials, the precision of the manufacturing process, and the intended functional performance. While traditional ceramics focus on bulk properties and cost-effectiveness, advanced ceramics are engineered for extreme environments and specialized technological functions.

2

Discuss the following structures with illustrations

15 marks
a

Perovskite

5 marks

Answer

The Perovskite structure has the general formula ABO3, exemplified by CaTiO3. In this cubic unit cell, the large A-site cation (e.g., Ca2+) occupies the corners of the cube (coordinate number 12), the smaller B-site cation (e.g., Ti4+) sits at the body-centered position (coordinate number 6), and oxygen anions occupy the face-centered positions. The structure is characterized by a network of corner-sharing BO6 octahedra with the A-site cation located in the large interstitial space between these octahedra.

b

ZnS

5 marks

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c

NaCl

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3

Calculate the coordination number and density of magnesia from the following data : radius of magnesium ion = 0.66 Å; radius of oxygen ion = 1.32 Å; the atomic weights are 24.3 g/g mole and 16 g/g mole for magnesium and oxygen respectively. MgO has NaCl structure.

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4

Illustrate and identify various lines, areas, and phases in the Al2O3-SiO2 phase diagram.

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Answer

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5

Describe the important ceramics and their properties for use in

15 marks
a

Magnetic applications

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b

Thermal applications

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c

Optical applications

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6

Explain sol and gel process and co-precipitation process using a flow chart.

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7

Using an illustration explain the HIP process and mention its advantages and disadvantages.

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8

Explain slip casting of ceramics with a neat illustration and mention its advantages and disadvantages.

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About this paper

This page contains the solved question paper with answers of SCIENCE AND TECHNOLOGY OF CERAMICS from Jawaharlal Nehru Technological University Hyderabad for B.Tech MME-MMT IV I, March - 2021, R16.

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