Jawaharlal Nehru Technological University Hyderabad
Jawaharlal Nehru Technological University Hyderabad B.Tech IV SCIENCE AND TECHNOLOGY OF CERAMICS Previous Question Paper (March - 2021 - R16)
Answer any Five Questions
All Questions Carry Equal Marks
Main
With the help of a flow sheet classify the ceramics. Explain.
Answer
Ceramics are broadly classified based on their application, chemical composition, and processing methods. The primary classification divides them into traditional and advanced (engineering) ceramics.
The classification flow sheet is as follows:
- Ceramics
- Traditional Ceramics
- Clay products (Bricks, tiles, pottery)
- Refractories (Fire bricks, crucibles)
- Glass (Soda-lime, borosilicate)
- Cements (Portland cement, hydraulic binders)
- Abrasives (Natural abrasives)
- Advanced Ceramics
- Oxide Ceramics (Alumina, Zirconia, Magnesia)
- Non-Oxide Ceramics (Carbides, Nitrides, Borides)
- Composite Ceramics (Ceramic matrix composites)
- Traditional Ceramics
Traditional Ceramics are primarily based on naturally occurring raw materials like clay, silica, and feldspar. They are typically produced in large volumes and are used in construction, domestic applications, and industrial refractory linings. Their properties are generally dictated by the mineralogy of the starting clays and firing temperatures.
Advanced Ceramics, also known as technical or engineering ceramics, are synthesized from high-purity, man-made chemical compounds. They are processed under strictly controlled conditions to achieve specific mechanical, thermal, electrical, or optical properties. These materials are essential for high-performance applications such as aerospace components, electronic substrates, cutting tools, and biomedical implants.
The distinction between these two categories lies in the purity of raw materials, the precision of the manufacturing process, and the intended functional performance. While traditional ceramics focus on bulk properties and cost-effectiveness, advanced ceramics are engineered for extreme environments and specialized technological functions.
Discuss the following structures with illustrations
Perovskite
Answer
The Perovskite structure has the general formula ABO3, exemplified by CaTiO3. In this cubic unit cell, the large A-site cation (e.g., Ca2+) occupies the corners of the cube (coordinate number 12), the smaller B-site cation (e.g., Ti4+) sits at the body-centered position (coordinate number 6), and oxygen anions occupy the face-centered positions. The structure is characterized by a network of corner-sharing BO6 octahedra with the A-site cation located in the large interstitial space between these octahedra.
ZnS
Answer
Sign in to view the complete answer paper.
NaCl
Answer
Sign in to view the complete answer paper.
Calculate the coordination number and density of magnesia from the following data : radius of magnesium ion = 0.66 Å; radius of oxygen ion = 1.32 Å; the atomic weights are 24.3 g/g mole and 16 g/g mole for magnesium and oxygen respectively. MgO has NaCl structure.
Answer
Sign in to view the complete answer paper.
Illustrate and identify various lines, areas, and phases in the Al2O3-SiO2 phase diagram.
Answer
Sign in to view the complete answer paper.
Describe the important ceramics and their properties for use in
Magnetic applications
Answer
Sign in to view the complete answer paper.
Thermal applications
Answer
Sign in to view the complete answer paper.
Optical applications
Answer
Sign in to view the complete answer paper.
Explain sol and gel process and co-precipitation process using a flow chart.
Answer
Sign in to view the complete answer paper.
Using an illustration explain the HIP process and mention its advantages and disadvantages.
Answer
Sign in to view the complete answer paper.
Explain slip casting of ceramics with a neat illustration and mention its advantages and disadvantages.
Answer
Sign in to view the complete answer paper.