JAWAHARLAL NEHRU TECHNOLOGICAL UNIVERSITY HYDERABAD

UNIT - I

Review of Thermodynamic Laws and Corollaries: Transient flow analysis, Second law thermodynamics, Entropy, Availability and unavailability, Thermodynamic potential. Maxwell relations, Specific heat relations, Mayer's relation. Entropy generation, Irreversibility-Gay Stodal equation.

UNIT - II

Ideal and Real gases: Equation of state, Real gas behavior, Vander Waal's equation, Generalization compressibility factor. Energy properties of real gases. Vapour pressure, Clausius, Clapeyro equation. Throttling, Joule. Thompson coefficient. Non reactive mixtures of perfect gases. Governing laws, Evaluation of properties, Psychometric mixture properties and psychometric chart, Air conditioning processes, cooling towers. Real gas mixtures.

UNIT - III

Combustion: Combustion Reactions, Enthalpy of formation. Entropy of formation, Reference levels of tables. Energy of formation, Heat of reaction, Adiabatic flame temperature, Enthalpies, Equilibrium. Chemical equilibrium of ideal gas, The Vant Hoff's equation. The chemical potential and phase equilibrium. The Gibbs phase rule.

UNIT - IV

Power Cycles: Review binary vapour cycle, co-generation and combined cycles, Second law analysts of cycles. Refrigeration cycles. Thermodynamics of irreversible processes. Introduction, Phenomenological laws, Onsaga Reciprocity relation, Applicability of the Phenomenological relations, Heat flux and entropy production, Thermodynamic phenomena, Thermo electric circuits.

UNIT - V

Direct Energy Conversion Introduction: Fuel cells, Thermo electric energy, Thermo ionic power generation, Thermodynamic devices magneto hydronamic generations, Photovoltaic cells.

REFERENCES:

• 1. Thermodynamics/Holman/ McGraw Hill.
• 2. Basic and Applied Thermodynamics/ P.K. Nag/ TMH
• 3. Thermodynamics/Sonnatag & Van Wylen / John Wiley & Sons
• 4. Thermodynamics for Engineers/Doolittle-Messe/ John Wiley & Sons
• 5. Engg. Thermodynamics/PL. Dhar / Elsevier
• 6. Irreversible Thermodynamics/HR De Groff.
• 7. Applied Thermodynamics – R. K. Rajput – Laxmi Publications
• 8. Engineering Thermodynamics/Chatopadyaya